Development of novel Lewis acid catalyzed cycloisomerizations: synthesis of bicyclo[3.1.0]hexenes and cyclopentenones
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چکیده
The Lewis acid catalyzed cyclization of hexatrienes and pentadienals to bicyclo[3.1.0]hexenes and cyclopentenones, respectively, was investigated. The application of the former reaction to the total synthesis of photodeoxytridachione, a molluscan polypropionate, is described. q 2003 Elsevier Ltd. All rights reserved.
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تاریخ انتشار 2003